The impact of these imperfections, which range from native 'point defects' to 'higher dimensional defects,' on solar cell efficiency is summarized and investigated.
How do defects affect the performance of solar cells?
Defects induce deep energy levels in the semiconductor bandgap, which degrade the carrier lifetime and quantum efficiency of solar cells. A comprehensive knowledge of the properties of defects require electrical characterization techniques providing information about the defect concentration, spatial distribution and physical origin.
Do shallow and deep level defects affect solar cell performance?
Next, we correlate the negative impact of shallow and deep level defects with solar cell performance as the former high density results in fermi-level pinning and the latter imposes NRR. Finally, we discuss the migration of these defects causing unintentional doping effects, anomalous hysteresis, and phase separation.
What are defects in solar cells based on perovskite-halides?
This Review describes what is known about the nature and impact of defects in solar cells based on perovskite-halides, with a focus on traps, recombination mechanisms, electrostatics, and defect conduction, which have an impact in both the bulk material and at the interfaces in devices.
How do point defects affect the performance of perovskite solar cells?
The performance of perovskite solar cells is significantly impacted by point defects, such as Schottky, Frenkel, interstitial vacancies, and substitutions. Interstitials (MA i, Pb i, I i) exert a significant influence on carrier concentration and modify the band structure within the material.
Do defects in light absorbing layers affect the performance of kesterite solar cells?
Defects in light-absorbing layers have indelible effects on the performance of kesterite solar cells. In the development of CZTSSe solar cells, a good understanding and effective engineering of the defects in CZTSSe absorbers have been demonstrated to be crucial factors for the fabrication of high-efficiency CZTSSe solar cells.
This reduces the gap between the quasi-Fermi levels, which sets the value of the open-circuit voltage, VOC, for the solar cell. Thus, the external electroluminescence quantum efficiency (EQE EL) of the solar cell is directly related to its VOC under illumination 17.